Heteropolyacids as an efficient and reusable catalytic system for the regiospecific nitration of phenols with metal nitrates

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A Reinvestigation of Nitration of Phenols with Metal Nitrates under Non-Aqueous and Aprotic Conditions

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a reinvestigation of nitration of phenols with metal nitrates under non-aqueous and aprotic conditions

nitration of phenol and various 4-substituted phenols with cu(no3)2.3h2o, cu(no3)2.3h2o/sio2, 9h2o and cr(no3)2. 9h2o in different anhydrous organic solvents are investigated. high selectivity ratio of para vs ortho isomers has been observed. mono- and dinitro compounds from phenol and 4-substituted phenols by choosing the proper solvents and reaction conditions, are also obtained with high sel...

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Nano TiO2 supported on SiO2 (Nano TiO2@SiO2) as a solid Lewis acid, was described to be an effective and reusable catalyst for one-pot three-component reaction of benzil, aryl aldehydes and ammonium acetate for the synthesis 2-aryl-4,5-diphenyl-1H-imdazoles synthesis. To explore the high efficacy of the catalytic system the four-component cyclization of benzil, aryl aldehydes, ammonium acetate ...

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ژورنال

عنوان ژورنال: Bulletin of the Chemical Society of Ethiopia

سال: 2012

ISSN: 1011-3924

DOI: 10.4314/bcse.v26i1.17